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Department of Chemical Engineering and Biotechnology

Research

Thodoris' research interests include chemical reaction engineering and process intensification, targeting to the development of novel materials and processes for heavy industry decarbonisation, high-value chemicals production and energy storage. During his PhD thesis, Thodoris focused on the carbonate looping technology and its application for the decrease of the carbon footprint of cement manufacturing, the intensification of natural gas reforming for high-purity H2 production and the demonstration of integrated CO2 capture and utilization. His experimental work consisted of the synthesis of CO2 capture materials and oxygen carriers/catalysts and the in-depth investigation of their activity under fixed or fluidised bed reactor experiments. His work is complemented with detailed thermodynamic and exergy analysis, process design, technoeconomics and life-cycle assessment of intensified CO2 capture processes. In his current study as postdoctoral researcher, Thodoris explores novel chemical looping processes for grid energy storage and NH3 production, two sectors whose state-of-the-art technologies have heavy environmental impact, thereby needing the development of more sustainable processes. Research on thermochemical energy storage aims to identify efficient chemical loops and materials that attain high and stable energy storage density. Similarly, the main challenge for chemical looping ammonia production is to develop materials with rapid kinetics for N2 activation and subsequent hydrogenation.

Biography

Thodoris is a chemical engineer that graduated from the Aristotle University of Thessaloniki, Greece in November 2018 with a GPA of 8.85 out of 10 (3rd in a class of 120 students). In December 2018, Thodoris started his Ph.D. at the Laboratory of Petrochemical Technology in the Department of Chemical Engineering of the Aristotle University of Thessaloniki, under the supervision of Prof. Angeliki A. Lemonidou, from where he graduated in November 2023 with distinction. Since January 2024, Thodoris has been working as a postdoctoral research associate in the Department of Chemical Engineering and Biotechnology of the University of Cambridge, UK. So far his work has been published in 10 articles in peer-review journals and has been presented via numerous contributions in international conferences and symposia.

Publications

Key publications: 

Google Scholar

1. Papalas T., Lypiridis D., Antzaras, A.N., Lemonidou A.A., Experimental investigation of integrated CO2 capture and conversion to syngas via calcium looping coupled with dry reforming of CH4, Chem. Eng. J., 2024, 485, 149866 doi.org/10.1016/j.cej.2024.149866 

2. Papalas T., Antzaras A.N., Lemonidou A.A., Unravelling the role of Co in mixed Ni-Co oxygen carriers/catalysts for H2 production via sorption enhanced steam methane reforming coupled with chemical looping, Appl. Catal. B: Environ. Energy, 2024, 247, 123777 doi.org/10.1016/j.apcatb.2024.123777 

3. Papalas T., Palamas E., Antzaras A.N., Lemonidou A.A., Evaluating bimetallic Ni-Co oxygen carriers for their redox behavior and catalytic activity toward steam methane reforming, Fuel, 2024, 359, 130272 doi.org/10.1016/j.fuel.2023.130272 

4. Antzaras A.N., Papalas T., Heracleous E., Kouris Ch., Techno-economic and environmental assessment of CO2 capture technologies in the cement industry, J. Clean. Prod., 2023, 428, 139330, doi.org/10.1016/j.jclepro.2023.139330 

5. Papalas T., Polychronidis, I., Antzaras, A.N., Lemonidou A.A., Enhancing the intermediate Temperature CO2 capture efficiency of mineral MgO via molten alkali nitrates and CaCO3: Characterization and sorption mechanism, 2021, J. CO2 Util., 50, 101605, doi.org/10.1016/j.jcou.2021.101605 

 

Other publications: 

1. Papalas T., Advancing the carbonate looping concept for applications in post-combustion CO2 capture and Η2 production via intensified reforming of CH4 processes, PhD thesis, 10.12681/eadd/55229 

2. Papalas T., Antzaras A.N., Lemonidou A.A., Integrated CO2 capture and utilization by combining calcium looping with CH4 reforming processes: A thermodynamic and exergetic approach, Energy & Fuels, 2024 doi.org/10.1021/acs.energyfuels.4c01462 

3. Papalas T., Antzaras, A.N., Lemonidou A.A., Magnesite-derived MgO promoted with molten salts and limestone as highly-efficient CO2 sorbent, 2021, J. CO2 Util., 53, 101725, doi.org/10.1016/j.jcou.2021.101725 

4. Papalas T., Antzaras, A.N., Lemonidou A.A., Evaluation of calcium-based sorbents derived from natural ores and industrial wastes for high-temperature CO2 capture, Ind. & Eng. Chem. Res., 2020, 59(21), 9926-9938, doi.org/10.1021/acs.iecr.9b06834 

5. Papalas T., Antzaras, A.N., Lemonidou A.A., Intensified steam methane reforming coupled with Ca-Ni looping in a dual fluidized bed reactor system: A conceptual design, Chem. Eng. J., 2020, 382, 122993, doi.org/10.1016/j.cej.2019.122993 

6. Darda S., Papalas T., Zabaniotou A., Biofuels journey in Europe: Currently the way to low carbon economy sustainability is still a challenge, J. Clean. Prod., 2019, 208, pp 575–588, doi.org/10.1016/j.jclepro.2018.10.147 

 

Postdoctoral Research Associate

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